Ah, my bad I misread it and thought you were asking for 12V@ 100 amps continuous. Those specialized ones are available, but are industrial/bespoke, and expensive. A quick look online and definite voltage relays like youre asking can range in the hundreds of dollars, depending on what you spec out. You
could male an EV vehicle contactor work, but as
@Lichen Bark pointed out, it sounds like you really want an automatic transfer switch. Not to mention, depending on the locality you're in, you might be required by local codes to have a transfer switch if you have an off-grid generator. You don't want to be held liable if the power goes out and the power company is out working on downed lines when you fire up your generator and backfeed electricity into the grid, frying a lineman to a crisp.